Interactions des alcynes avec les complexes carbéniques du tungstène portant une double liaison carbone— carbone: Accès aux dérivés bicyclo[4,1,0]. Download Citation on ResearchGate | Réaction des halogenures de titane(IV) avec les alcynes: Formation d’halogénoalcènes | The behaviour of some mono-. Download Citation on ResearchGate | Action du chlorure de fer(III) sur les alcynes: Reduction du fer(III) en fer(II) et formation d’un chloro-alcene | The behaviour.

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A unique role in the addition of diazoalkane carbene to alkynes. In addition, the results of the theoretical investigation of Chapter 2 are exploited to show how changes in the phosphorus substituents can be used to fine tune regioselectivity of alkyne cycloadditions without modifying the substituents on the final product. Catalysis, Ruthenium, Diazo compounds, Carbene, Alkynes. Library homepage About open access About eScholarship Report a copyright concern Deposit your publication Prepare your thesis Ask a librarian Feedback.

Method for producing distillate from a hydrocarbon feed, comprising alcohol condensation. Houk et le Dr. Importantly, these 1,3-dipoles display divergent regioselectivity, which can be exploited to synthesize a variety of pyrroles with high selectivity through the use of the appropriate reactant.

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Library homepage About open access About eScholarship Report a copyright concern. Substrate specificity and enantioselectivity of 4-hydroxyacetophenone monooxygenase. X-ray crystallographic studies demonstrate the significant role of the PR3 unit on the ground state structure of these dipoles and their alcymes.


The utility of this reaction has been extended to other products, including in situ reduction of the 2-pyrroline to pyrolidines, or oxidation to form pyrroles. Access to the full text of this article requires a subscription. Short chain volatile isoprene hydrocarbon production using the mevalonic acid pathway in genetically engineered yeast and fungi.

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Hydratation des alcynes

Methods of refining and producing dibasic esters and acids from natural oil feedstocks. Access to the PDF text. Similarly, the rational on regioselectivity also allows the prediction of regioselectivity for a wide scope of alkynes. Double catalytic addition of diazo compounds to alkynes: Malonyl-coenzyme A reductase in alcnes modified 3-hydroxypropionate cycle for autotrophic carbon fixation in archaeal Metallosphaera and Sulfolobus spp.

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Catalytic addition of diazoalkane carbene to enynes: Deposit your publication Prepare your thesis Ask alynes librarian Feedback. Catalysts for partial oxidation of hydrocarbons and method of partial oxidation of hydrocarbons.

Access alvynes the text HTML. Enantioselective reduction of carbonyl compounds by whole-cell biotransformation, combining a formate dehydrogenase and a R -specific alcohol dehydrogenase. Different phosphites and phosphonites are tested for their ability to mediate intramolecular cycloaddition with alkenes, and optimum results are obtained with 2-catechyl PPh. Previous Article Gecom-Concoord Polycyclic 2-pyrrolines are generated in rapid cycloaddition reactions, in a modular fashion from easily accessible starting materials: Molecular characterization pes genes of Pseudomonas sp.

Cloning and nucleotide sequence of fosfomycin biosynthetic genes of Streptomyces wedmorensis.

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Conjointement avec le Pr. Method for producing c9-alcohols a,cynes method for the integrated production of c9-alcohols and calcohols. As per the Law relating to information storage and personal integrity, you have the right to oppose art 26 of that lawaccess art 34 of that law and rectify art 36 of that law your personal data. You can move this window by clicking on the headline. Kind code of ref document: The owners of this website hereby guarantee to respect the legal confidentiality conditions, applicable in France, and not to disclose this data to third parties.


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Title Creator Subject Faculty Date. The University’s open access institutional repository: If you want to subscribe to this journal, see our rates You can purchase this item in Pay Per View: Applications of new phosphorus-based 1,3-dipolar cycloaddition reagents in nitrogen heterocycle synthesis.

Personal information regarding our website’s visitors, including their identity, is confidential. Catalytic addition of diazoalkane carbene to propargylic compounds: All items in eScholarship McGill are protected by copyright with all rights reserved unless otherwise indicated.

Direct route to alkenyl alkylidene bicyclohexane derivatives. Propargylic carboxylates lead to conjugated dienes by coupling led the diazoalkane carbene with the alkyne terminal carbon and 1,2-shift of the carboxylate.

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